Toxic air pollutants, also called Hazardous Air Pollutants (HAPs), are known or suspected to cause adverse health or environmental effects. Most air toxics originate from human activities such as vehicle emissions, factories, solvents, etc. The Clean Air Act (CAA) requires EPA to regulate emissions of toxic air pollutants from a published list of industrial sources referred to as "source categories." These sources must meet control technology requirements for toxic air pollutants.
The EPA is required to develop regulations for all industries that emit one or more of the pollutants in significant quantities. Ambient Air Toxic Monitoring is an important part of the efforts to control air toxics pollutant which consists of both national and community-scale programs. The ATMN consists of three separate monitoring programs: The Urban Air Toxics Monitoring Network (UATM), The National Air Toxics Trends Stations (NATTS), and The Community Assessment Monitoring program (CAMP).
The Virginia Department of Environmental Quality currently operates two ambient air toxics monitoring programs in Virginia:
1. National Air Toxics Trends Stations network:
The Air Toxics Monitoring Steering Committee was established in 1999 to oversee the development of a national air toxics monitoring network. In 2002, EPA deployed the National Air Toxics Trends Stations (NATTS) network. The objective for the NATTS network is to provide long-term monitoring data for a limited number of air toxics across representative areas of the country in order to establish overall trends for these pollutants. The required pollutants included Volatile Organic Compounds (VOCs), Carbonyls, PM10 metals, Hexavalent chromium, and Polycyclic Aromatic Hydrocarbons (PAHs).
The NATTS network currently consists of 27 sites (20 urban, 7 rural) across the United States. In July 2008, the Virginia Department of Environmental Quality began operating a NATTS located at the MathScience Innovation Center, 2401 Hartman Street, Richmond.
|
Roxbury MA
|
MA Department of Environmental Protection
|
25-025-0042
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Providence
|
RI Department of Environmental Management
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44-007-0022
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Underhill VT
|
VT Department of Environmental Conservation
|
50-007-0007
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Bronx NY
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NY Department of Environmental Conservation
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36-005-0110
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Rochester NY
|
NY Department of Environmental Conservation
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36-055-1007
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Washington DC
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DC Department of Health
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11-001-0043
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Richmond VA
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VA Department of Environmental Quality
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51-087-0014
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Tampa FL
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Hillsborough County Environmental Protection Commission
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12-057-3002
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Pinellas County FL
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Pinellas County Department of Environmental Management
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12-103-0026
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Atlanta GA
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KY Department of Environmental Protection
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21-193-0003
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Grayson Lake KY
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KY Department of Environmental Protection
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21-043-0500
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Chesterfield SC
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SC Department of Health and Environmental Conservation
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45-025-0001
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Detroit MI
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MI Department of Environmental Quality
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26-163-0033
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Chicago IL
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WI Department of Natural Resources
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55-027-0007
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Horicon WI
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WI Department of Natural Resources
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55-027-0001
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Houston TX
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TX Commission on Environmental Quality
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48-201-1039
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Harrison County TX
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TX Commission on Environmental Quality
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48-203-0002
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St. Louis MO
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MO Department of Natural Resources
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29-510-0085
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Bountiful UT
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UT Department of Environmental Quality
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49-011-0004
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Grand Junction CO
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CO Department of Health and Environment
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08-077-0017/18
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San Jose CA
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Bay Area Air Quality Management District
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06-085-0005
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Phoenix AZ
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AZ Department of Environmental Quality
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04-013-9997
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Los Angeles CA
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South Coast Air Quality Management District
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06-037-1103
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Rubidoux CA
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South Coast Air Quality Management District
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06-065-8001
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Seattle WA
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WA Department of Ecology
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53-033-0080
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La Grande OR
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OR Department of Environmental Quality
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41-061-0119
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Portland OR
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OR Department of Environmental Quality
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41-051-0246
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2. Urban Air Toxics Monitoring network:
In 2002, The Virginia Department of Environmental Quality established Urban Air Toxic Monitoring Stations as part of Air Toxics Monitoring Network. These stations are the State / EPA Region III cooperative-monitoring sites supported by a special 103 Grant and the Performance Partnerships Grant (PPG). Data collected from these sites are used to characterize the present urban air toxic concentrations including trend analysis. The UATM allows DEQ to assess the reasonableness of the National Air Toxics Assessment (NATA).
The NATA estimates emissions and health risk information on selected-air toxics pollutants and diesel particulate matter (diesel PM) (
list of selected target compounds - PDF). EPA operates a web site, which contains current information concerning the NATA program and activities. This web site is located at
http://www.epa.gov/ttn/atw/nata/.
Virginia currently operates three UATM sites, which are shown in the following table.
|
Fairfax
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Lee Regional District Park
Telegraph Road and Rode Hill Dr.
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46-B9
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51-059-0030
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Hopewell
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Carter G. Woodson Middle School
1000 Winston Churchill Drive
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154-M
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51-670-0010
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Virginia Beach
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DEQ Tidewater Regional Office
5636 Southern Blvd
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184-J
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51-810-0008
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Sampling at the UATM sites consists of ambient air samples. These samples take three different forms. The first is ambient air samples collected in canisters for the capture of VOCs. The second is ambient air drawn through DNPH treated cartridges to collect Carbonyls. The third form passes ambient air through quartz filters to collect a range of particulate matter.
The sampling frequency is one 24-hour canister sample, one 24-hour DNPH coated Carbonyl cartridge, and one 24-hour Total Suspended Particulate (TSP) filter on every 6th day. The target pollutants are included in the list of 188 HAPs and some selected metals.
Canister samples are collected in a specially deactivated 6-liter canister. Integrated, whole air samples are collected using a mass flow controlled sampler. Canister samples are analyzed at the Maryland Department of the Environment Air Lab using Gas Chromatography and a Mass Spectrometer (GC/MS) by EPA Method TO14/15. A list of TO14/15 target compounds may be viewed by clicking on the following link. (
TO14/15 target compounds - PDF)
Carbonyl samples are analyzed at the Air Management Laboratory of Philadelphia for 6 Carbonyl compounds using liquid chromatography by EPA method TO-11. These target compounds may be viewed by clicking on the following link. (
Carbonyl target compounds - PDF)
Filter samples are weighed and analyzed by the Virginia Division of Consolidated Laboratory Services for some selected metals. The target compounds may be viewed by clicking on the following link. (
target metals - PDF)
The above laboratories have been designated as the EPA region III laboratories for their respective analysis.
Additional information
The Plain English Guide to the Clean Air Act (CAA) is a web site maintained by the EPA. This web site can be found at http://www.epa.gov/airquality/peg_caa/index.html. This web site attempts to demystify the CAA and use plain English to explain the requirements set forth in the CAA.
Methods of analysis may be viewed by clicking on the following links:
Questions concerning any variations to the above methods would need to be directed to the laboratory performing the specific analysis located below.
| Dennis Sosna |
City of Philadelphia
Deptartment of Public Health
Carbonyl Group
Air Management Services Laboratory |
1501 E. Lycoming Street
Philadelphia, PA 19124 |
| Walter Cooney |
Maryland Department of the Environment
Air and Radiation Management Administration |
1800 Washington Blvd., STE 110
Baltimore, Maryland 21230-1721 |
| Todd Jackson |
West Virginia Department of Environmental Protection
Division of Air Quality
Guthrie Lab |
4900 Brenda Lane
Bldg. 14
Charleston, WV 25312 |
Questions concerning the DEQ Ambient Air Toxics Monitoring Program should be directed to:
Baxter Gilley
Office of Air Quality Monitoring
4949-C Cox Road
Glen Allen, VA 23060
Voice: 804-527-5188
Fax: 804-527-5160
Email: Baxter.Gilley@deq.virginia.gov